Synthesis and Crystal Structure of a Chiral C3-Symmetric Monophosphane
β Scribed by Dr. Carsten Bolm; Dr. William M. Davis; Dr. Ronald L. Halterman; Prof. Dr. K. Barry Sharpless
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 327 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
By use of an asymmetric Ullmann coupling involving chiral naphthalene oxazolines 1, the title compounds were prepared in good yields and with high diastereoselectivity. Hydrolysis of the binaphthyl oxazolines 2 led to the di-aldehydes 5, which were transformed into the azepine derivative, 6. The lat
## Abstract Two novel chiral rhodium complexes were successfully synthesized from the reaction of chiral bidentate nitrogen ligands with RhCl~3~Β·3H~2~O in ethanol under reflux. Their unusual crystal structures were unambiguously obtained by Xβray analysis. Copyright Β© 2001 John Wiley & Sons, Ltd.