Synthesis and Coordination Chemistry of the New Unsymmetrical Ligand Ph2PCH2NHC6H4PPh2
✍ Scribed by Qingzhi Zhang; Stephen M. Aucott; Alexandra M. Z. Slawin; J. Derek Woollins
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 242 KB
- Volume
- 2002
- Category
- Article
- ISSN
- 1434-1948
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📜 SIMILAR VOLUMES
H,-elimination from 3 must also occur [Eq. (e)]."ll Note that this equilibrium involves the same 16-electron species implicated in Equation (c). The product-forming hydrido-ethyl (A) and hydridoethyl ethylene (B) species (Scheme 1) "downstream" of reaction (d) have not been observed under a variety
## Abstract Thermolysis of Ru(IMes)(dppp)(CO)H~2~ (1, IMes=1,3‐dimesityl‐1,3‐dihydro‐2__H__‐imidazol‐2‐ylidene; dppp=Ph~2~PCH~2~CH~2~CH~2~PPh~2~) in the presence of trimethylvinylsilane yields Ru(IMes')(dppp)(CO)H (2) resulting from intramolecular ArCH~2~–H CH bond activation of the __N__‐heterocy