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Photochemical 1,2 Shift of the Phosphane Ligands in the Silanediyl Complex [(2-Ph2PCH2C6H4)2SiCr(CO)5]

✍ Scribed by Dr. Hermann Handwerker; Dipl.-Chem. Martin Paul; Dr. Janet Blümel; Dr. Christian Zybill


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
391 KB
Volume
32
Category
Article
ISSN
0044-8249

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## Abstract Thermolysis of Ru(IMes)(dppp)(CO)H~2~ (1, IMes=1,3‐dimesityl‐1,3‐dihydro‐2__H__‐imidazol‐2‐ylidene; dppp=Ph~2~PCH~2~CH~2~CH~2~PPh~2~) in the presence of trimethylvinylsilane yields Ru(IMes')(dppp)(CO)H (2) resulting from intramolecular ArCH~2~–H CH bond activation of the __N__‐heterocy