Synthesis and Conformational Analysis of Optically Active Ferrocene Containing Macrocyclic Peptides
✍ Scribed by Maricic, Suzana; Frejd, Torbjörn
- Book ID
- 118039503
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 311 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
The homochiral 3-amino-1-(4-methoxyphenyl)-4-phenyl-βlactam (ϵ Alm) was conjugated with Boc-Ala to give Ala-Alm (9) after Boc deprotection (Boc = tert-butoxycarbonyl, Ala = alanine). Coupling of Fc-COOH (1) and Boc-Fca (10) with "dipeptide" 9 resulted in the formation of Fc-CO-Ala-Alm ( ) and the tr
## Abstract Ferrocene‐containing dipeptides Ac‐Fca‐AA‐OMe (AA = L‐Val, L‐Ile) with the artificial amino acid 1'‐aminoferrocene‐1‐carboxylic acid (Fca) and chiral α‐amino acid building blocks display hydrogen‐bonded structures that result in organised helical ferrocene units in solution, as evidence