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Synthesis and chemistry of a new P-N chelating ligand; (R) and (S)-6-(2′-diphenylphosphino-1′-naphthyl)phenanthridine

✍ Scribed by Jean-Marc Valk; Timothy D.W Claridge; John M Brown; David Hibbs; Michael B Hursthouse


Book ID
108036345
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
817 KB
Volume
6
Category
Article
ISSN
0957-4166

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Synthesis of 4-(2-diphenylphosphino-1-na
✍ V Gautheron Chapoulaud; J Audoux; N Plé; A Turck; G Quéguiner 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 168 KB

We describe a multistep synthesis leading in a good yield to the title compound. The biaryl linkage was formed in a Pd-catalysed coupling of 2-phenyl-4-chloroquinazoline with 2-methoxy-l-naphthylboronic acid. A further metal-catalysed reaction gave the formation of the naphthylphosphorus bond allowi