Synthesis and Characterization of Triptych μ-ABC Star Triblock Copolymers
✍ Scribed by Li, Zhibo; Hillmyer, Marc A.; Lodge, Timothy P.
- Book ID
- 127305572
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 122 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0024-9297
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## Abstract This study describes the synthesis of amphiphilic ABC‐triblock copolymers comprising a central pseudopoly(4‐hydroxy‐L‐proline) segment and terminal hydrophilic poly(ethylene glycol)methyl ether as well as hydrophobic poly(ε‐caprolactone) blocks. Differential scanning calorimetry, ^1^H‐N
## Abstract The stability of hierarchical lamellar morphologies formed in ABC star triblock copolymers, is studied using the self‐consistent mean‐field theory. The hierarchical lamellae consist of repeating period of the largest block A‐formed layer and B/C coformed layer where B and C domains are