Synthesis and characterization of the pentacoordinate mononitrosyliron complexes Fe(NO)[SCH2CH2N(CH3)(CH2)nN(CH3)CH2CH2S], n = 2,3
β Scribed by Karlin, Kenneth D.; Rabinowitz, Harold N.; Lewis, David L.; Lippard, Stephen J.
- Book ID
- 126854844
- Publisher
- American Chemical Society
- Year
- 1977
- Tongue
- English
- Weight
- 889 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0020-1669
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Rate constants for the reactions of OH radicals and Cl atoms with CH,CH,NO>, CH,CH,CH,NO,, CH3CH2CH2CHzN02, and CH,CH2CH2CH,CH2N02 have been determined at 295+3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis co
The structures ofcthylidcne and propylidene in their lowest singlet states :ue considered using INDO lnd MIND 112 calculations. Using a gadicnt optimization method, it is found that R!INDO/Z predicts no encrg minimu.n f-or singlet ethylidenc, while INDO predicts non-&ssic4 bridged structures for the