Effect of variations of the size and structure of the principal alkyl group on alkene elimination from the immonium ions CH3CH2CHN+(CH3)R, CH3CH2CH2CHN+(CH3)R and CH3CH2CH2CH2CHN+(CH3)R
✍ Scribed by Simon J Mandeville; Richard D Bowen; Moschoula A Trikoupis; Johan K Terlouw
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 379 KB
- Volume
- 199
- Category
- Article
- ISSN
- 1387-3806
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The structures ofcthylidcne and propylidene in their lowest singlet states :ue considered using INDO lnd MIND 112 calculations. Using a gadicnt optimization method, it is found that R!INDO/Z predicts no encrg minimu.n f-or singlet ethylidenc, while INDO predicts non-&ssic4 bridged structures for the
Rate constants for the reactions of OH radicals and Cl atoms with CH,CH,NO>, CH,CH,CH,NO,, CH3CH2CH2CHzN02, and CH,CH2CH2CH,CH2N02 have been determined at 295+3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis co
A study of the reaction initiated by the thermal decomposition of di-t-butyl peroxide (DTBP) in the presence of (CHa)?C=CHz (B) at 391-444 K has yielded kinetic data on a number of reactions involving CH3 (M.), (CH&CCHzCH3 (MB.) and ( C H ~) ~C C H ~C ( C H ~) Z C H ~C H ~ (MBB.) radicals. The cross