Investigation of the equilibria of the reaction: CH3(CH2)4OH + (CH3)2C: CH2 = CH3(CH2)4OC(CH3)3
β Scribed by A.M Rozhnov; V.I Barkov; K.G Sharonov; V.S Tsvetkov
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 480 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0021-9614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The structures ofcthylidcne and propylidene in their lowest singlet states :ue considered using INDO lnd MIND 112 calculations. Using a gadicnt optimization method, it is found that R!INDO/Z predicts no encrg minimu.n f-or singlet ethylidenc, while INDO predicts non-&ssic4 bridged structures for the
Excess molar volumes at the temperature 298.15 K were measured for , and {xCH3(CH2)4 CH3 +(1x)CH3(CH2)3OH}. Excess molar volumes were determined using an Anton Paar DMA 60/602 densimeter. The experimental values obtained in this work were compared with results obtained using methods which estimate
Rate constants for the reactions of OH radicals and Cl atoms with CH,CH,NO>, CH,CH,CH,NO,, CH3CH2CH2CHzN02, and CH,CH2CH2CH,CH2N02 have been determined at 295+3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis co
A study of the reaction initiated by the thermal decomposition of di-t-butyl peroxide (DTBP) in the presence of (CHa)?C=CHz (B) at 391-444 K has yielded kinetic data on a number of reactions involving CH3 (M.), (CH&CCHzCH3 (MB.) and ( C H ~) ~C C H ~C ( C H ~) Z C H ~C H ~ (MBB.) radicals. The cross