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Synthesis and Characterization of the Keggin-Type Ruthenium-Nitrido Derivative [PW 11 O 39 {RuN}] 4- and Evidence of Its Electrophilic Reactivity

✍ Scribed by Lahootun, Vanina; Besson, Claire; Villanneau, Richard; Villain, Françoise; Chamoreau, Lise-Marie; Boubekeur, Kamal; Blanchard, Sébastien; Thouvenot, René; Proust, Anna

Book ID
120938514
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
228 KB
Volume
129
Category
Article
ISSN
0002-7863

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A (Nitrido)chromium(V) Function Incorpor
A (Nitrido)chromium(V) Function Incorporated in a Keggin-Type Polyoxometalate: [PW11O39CrN]5– – Synthesis, Characterization and Elements of Reactivity
✍ Vanina Lahootun; Jeff Karcher; Christine Courillon; Franck Launay; Kristopher Mi 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 297 KB

## Abstract The (nitrido)chromium(V) derivative [PW~11~O~39~{CrN}]^5–^ (1a) was synthesized by the reaction of the monolacunary [H~3~PW~11~O~39~]^4–^ polyanion with a {CrN}^2+^ function generated in situ. The EPR spectrum of the formed polyoxometalate confirmed the presence of a paramagnetic Cr^V^