ChemInform Abstract: A (Nitrido)chromium(V) Function Incorporated in a Keggin-Type Polyoxometalate: [PW11O39CrN]5- — Synthesis, Characterization and Elements of Reactivity.

A (Nitrido)chromium(V) Function Incorpor

A (Nitrido)chromium(V) Function Incorporated in a Keggin-Type Polyoxometalate: [PW11O39CrN]5– – Synthesis, Characterization and Elements of Reactivity

✍ Vanina Lahootun; Jeff Karcher; Christine Courillon; Franck Launay; Kristopher Mi 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 297 KB

## Abstract The (nitrido)chromium(V) derivative [PW~11~O~39~{CrN}]^5–^ (1a) was synthesized by the reaction of the monolacunary [H~3~PW~11~O~39~]^4–^ polyanion with a {CrN}^2+^ function generated in situ. The EPR spectrum of the formed polyoxometalate confirmed the presence of a paramagnetic Cr^V^