## Abstract The (nitrido)chromium(V) derivative [PW~11~O~39~{CrN}]^5β^ (1a) was synthesized by the reaction of the monolacunary [H~3~PW~11~O~39~]^4β^ polyanion with a {CrN}^2+^ function generated in situ. The EPR spectrum of the formed polyoxometalate confirmed the presence of a paramagnetic Cr^V^
β¦ LIBER β¦
Synthesis and Characterization of the Keggin-Type Ruthenium-Nitrido Derivative [PW11O39{RuN}]4- and Evidence of Its Electrophilic Reactivity.
β Scribed by Vanina Lahootun; Claire Besson; Richard Villanneau; Francoise Villain; Lise-Marie Chamoreau; Kamal Boubekeur; Sebastien Blanchard; Rene Thouvenot; Anna Proust
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 21 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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Microwave irradiation for 15 minutes allowed the highly stable oxidation catalyst [PW 11 O 39 Ru II (DMSO)] 5-, as confirmed by 1 H, 31 P, 99 Ru and 183 W NMR techniques. selective hydrothermal synthesis of the diamagnetic, airgeometries of both 2 and 3 obtained with PM3(tm) semiem- [a