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Synthesis and Characterization of the Keggin-Type Ruthenium-Nitrido Derivative [PW11O39{RuN}]4- and Evidence of Its Electrophilic Reactivity.

✍ Scribed by Vanina Lahootun; Claire Besson; Richard Villanneau; Francoise Villain; Lise-Marie Chamoreau; Kamal Boubekeur; Sebastien Blanchard; Rene Thouvenot; Anna Proust


Publisher
John Wiley and Sons
Year
2007
Weight
21 KB
Volume
38
Category
Article
ISSN
0931-7597

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✍ Vanina Lahootun; Jeff Karcher; Christine Courillon; Franck Launay; Kristopher Mi πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 297 KB

## Abstract The (nitrido)chromium(V) derivative [PW~11~O~39~{CrN}]^5–^ (1a) was synthesized by the reaction of the monolacunary [H~3~PW~11~O~39~]^4–^ polyanion with a {CrN}^2+^ function generated in situ. The EPR spectrum of the formed polyoxometalate confirmed the presence of a paramagnetic Cr^V^

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Microwave irradiation for 15 minutes allowed the highly stable oxidation catalyst [PW 11 O 39 Ru II (DMSO)] 5-, as confirmed by 1 H, 31 P, 99 Ru and 183 W NMR techniques. selective hydrothermal synthesis of the diamagnetic, airgeometries of both 2 and 3 obtained with PM3(tm) semiem- [a