Synthesis and characterization of spiro[3.4]octa-5,7-diene
β Scribed by Miller, R. D.; Schneider, M.; Dolce, D. L.
- Book ID
- 126136758
- Publisher
- American Chemical Society
- Year
- 1973
- Tongue
- English
- Weight
- 257 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The photoelectron spectra of spiro[3.4]octane (**1**), spiro[3.4]octeneβ5 (**2**), spiro[3.4]βoctaβ5,7βdiene (**3**), spiro[4.4]noneneβ2 (**4**) and spiro[4.4]nonaβ2,4βdiene (**5**) have been recorded. The first bands of these spectra are correlated with orbitals which are Οβorbitals, _
We have recently succeeded in preparing a series of spiro[2.5]octa-k,i'-dien-6-ones (1) and find the photochemistry oftheae ccmpowds to differ from that reported (2a-c) for the parent dienone 2 (B-c). Schuster and coworkers report that irradiation (>28&) of an ethereal solution of 2 lmds to intermed