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A convenient synthesis of spiro[3.4]octa-5,7-diene

✍ Scribed by Ihsan Erden; Edmund M. Sorenson

Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
105 KB
Volume
24
Category
Article
ISSN
0040-4039

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## Abstract The photoelectron spectra of spiro[3.4]octane (**1**), spiro[3.4]octene‐5 (**2**), spiro[3.4]‐octa‐5,7‐diene (**3**), spiro[4.4]nonene‐2 (**4**) and spiro[4.4]nona‐2,4‐diene (**5**) have been recorded. The first bands of these spectra are correlated with orbitals which are π‐orbitals, _

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We have recently succeeded in preparing a series of spiro[2.5]octa-k,i'-dien-6-ones (1) and find the photochemistry oftheae ccmpowds to differ from that reported (2a-c) for the parent dienone 2 (B-c). Schuster and coworkers report that irradiation (>28&) of an ethereal solution of 2 lmds to intermed