Homopolymers and copolymers of acrylamide (AA) and acrylic acid (AAc) were synthesized by the free radical solution polymerization technique. Feed ratios of the monomers were 85 : 15 (w/w), 65 : 35 (w/w), and 50 : 50 (w/w) of acrylamide and acrylic acid, respectively, for synthesis of copolymers. Al
Synthesis and characterization of some soluble conducting polyazomethine polymers
β Scribed by El-Shekeil, Ali G.; Al-Saady, Hussein A.; Al-Yusufy, Fatma A.
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 252 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0959-8103
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β¦ Synopsis
Conducting crystalline polyazomethine polymers with high solubility and low melting points have been prepared and studied. The polymers were synthesized by the polycondensation of p-phenylene diamine and 2-nitro-pphenylene diamine with terephthaldehyde and p-diacetylbenzene. Polymers with polar functional groups and methyl side groups were found to be more NO 2 soluble in common organic solvents and to possess lower melting points. The polymers were studied using IR and UVΓvisible spectra, elemental analyses, solubility, inherent viscosity, X-ray di β raction, scanning electron microscopy and d.c. electrical conductivity.
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