Synthesis and Characterization of {Re(CO) 3 } 4- n {PtMe 3 } n (OH) 4 , ( n = 1−3). A Set of Heterobimetallic Hydroxy Cubane Complexes
✍ Scribed by Brand, Udo; Wright, Chris A.; Shapley, John R.
- Book ID
- 126842209
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 56 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0020-1669
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Electrochemical copolymerization of N 1,N 3-bis(thiophene-3-ylmethylene)benzene-1,3-diamine (TMBA) with 3,4-ethylenedioxythiophene (EDOT) was carried out in a CH3CN/LiClO4 (0.1 M) solvent-electrolyte via potentiodynamic electrolysis. Chemical structure of the monomer was determined by n
Compound 2 was synthesized in 4 steps in 65% overall yield. Mechanistic studies of the key pyrazole forming step revealed a tetrahyrofuran intermediate (10) of the starting l-(4-chlorophenyl)-6-hydroxyhexane-1,8dione (3). This intermediate reverses the normal regioselectivity observed in additions