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Carbonylnickelates. 3. Synthesis and chemical characterization of the [Ni12(CO)21H4-n]n- (n = 2, 3, 4) clusters

✍ Scribed by Ceriotti, Alessandro; Chini, Paolo; Della Pergola, Roberto; Longoni, Giuliano


Book ID
127110601
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
594 KB
Volume
22
Category
Article
ISSN
0020-1669

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Icosahedral Ga-Centred Nickel Carbonyl C
✍ Cristina Femoni; Maria Carmela Iapalucci; Giuliano Longoni; Stefano Zacchini πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 311 KB

## Abstract The reaction of [Ni~5~(CO)~12~]^2–^ or [Ni~6~(CO)~12~]^2–^ with GaCl~3~ in dichloromethane under a nitrogen atmosphere affords a mixture of [Ni~12+__x__~(ΞΌ~12~‐Ga)(CO)~22+__x__~]^3–^ (__x__ = 0–3) clusters. Short exposure of the above mixture to a carbon monoxide atmosphere leads to the