Metal phthalocyanines (M = Cu, Ni, Co, SnCI2) 3-6 containing four 14-membered tetraaza macrocycles have been prepared. Detosylation of the aza functions has provided donor sites for binding four Ni2+ ions giving a pentanuclear com-plex which is extremely soluble in polar solvents. The mass spectrum
✦ LIBER ✦
Synthesis and characterization of novel phthalocyanines substituted with four tetraaza macrocycles
✍ Scribed by Ko�ak, Makbule; Cihan, Ali; Okur, Ali �.; Bekaro?lu, �zer
- Book ID
- 120921762
- Publisher
- The Royal Society of Chemistry
- Year
- 1991
- Tongue
- English
- Weight
- 155 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0022-4936
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Symmetrically tetrasubstituted metal-free phthalocyanine 6 with four 14-membered dioxadithia macrocycles each of which is attached to a 15-membered crown ether has been prepared in a multi-step reaction sequence. The new compounds were characterized by elemental analysis, IR, 1 H and 13 C NMR, UV-vi