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Synthesis and Characterization of Phthalocyanines Containing Four 14-Membered Tetraaza Macrocycles

✍ Scribed by Koçak, Makbule ;Güek, Ayşegül ;Gül, Ahmet ;Bekaro??lu, Özer


Publisher
Wiley (John Wiley & Sons)
Year
1994
Tongue
English
Weight
452 KB
Volume
127
Category
Article
ISSN
0009-2940

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✦ Synopsis


Metal phthalocyanines (M = Cu, Ni, Co, SnCI2) 3-6 containing four 14-membered tetraaza macrocycles have been prepared. Detosylation of the aza functions has provided donor sites for binding four Ni2+ ions giving a pentanuclear com-plex which is extremely soluble in polar solvents. The mass spectrum of the [hexadecakis(N-p-tosy1)-tetrakis-macrocy- cle-phthalocyaninato]copper(II) 3 is described


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✍ A. R. Özkaya; İ. Yilmaz; Ö. Bekaroǧlu 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 172 KB 👁 2 views

Cyclic voltammetric measurements of Cu(II) and Ni(II) phthalocyanines with four 16membered diazadithia macrocycles (1 and 2) and pentanuclear Ni(II) phthalocyanine bearing four Cu(II) ions in diazadithia macrocycles at the peripheral positions (3) have been carried out on platinum in DMSO and in aqu