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Synthesis and Characterization of Novel Chiral 1,2-Diamines Derived from α-Pinene.
✍ Scribed by Toshiaki Suzuki; Akira Shibata; Naoya Morohashi; Yoshihiro Ohba
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 15 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Optically pure α‐diimines quantitatively obtained in solvent‐free conditions starting from 2,3‐butanedione and (__S__)‐(−)‐1‐phenylethylamine and (__S__)‐(−)‐1‐(4‐methylphenyl)ethylamine, respectively, yielded the new chiral mono‐Pd complexes 2a–b, which have been partly characterized b
A novel bismaleimide, 2,2Ј-dimethyl-4,4Ј-bis(4-maleimidophenoxy)biphenyl, containing noncoplanar 2,2Ј-dimethylbiphenylene and flexible ether units in the polymer backbone was synthesized from 2,2Ј-dimethyl-4,4Ј-bis(4-aminophenoxy)biphenyl with maleic anhydride. The bismaleimide was reacted with 11 d