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Synthesis and Characterization of Novel Biodegradable Copolymers of 5-Benzyloxy-1,3-dioxan-2-one and Glycolide

✍ Scribed by Si-Xue Cheng; Zhi-Mei Miao; Lian-Sheng Wang; Ren-Xi Zhuo

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 77 KB
Volume: 24
Category: Article
ISSN: 1022-1336
DOI: 10.1002/marc.200300085

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✦ Synopsis

Abstract

A series of novel biodegradable random copolymers of 5‐benzyloxy‐1,3‐dioxan‐2‐one (5‐benzyloxy‐trimethylene carbonate, BTMC) and glycolide were synthesized by ring‐opening polymerization. The copolymers were characterized by nuclear magnetic resonance (NMR) spectroscopy and gel permeation chromatography (GPC). The incorporation of BTMC units into the copolymer chains results in good solubility of the polymers in common solvents. The in vitro degradation rate can be tailored by adjusting the composition of the copolymers.

The in vitro degradation of the homopolymers and poly(BTMC‐co‐GA) copolymers.

magnified imageThe in vitro degradation of the homopolymers and poly(BTMC‐co‐GA) copolymers.

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