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Synthesis of copolymer of 1,3-dioxan-2-one and 2-hydro-2-oxo-1,3,2-dioxaphosphorinane

✍ Scribed by Bin Hu; Renxi Zhuo; Changlie Fan

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 263 KB
Volume: 9
Category: Article
ISSN: 1042-7147
DOI: 10.1002/(sici)1099-1581(199802)9:2<145::aid-pat742>3.0.co;2-c

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✦ Synopsis

A new type of copolymer was synthesized by ringopening polymerization of 1,3-dioxan-2-one (TMC) and 2-hydro-2-oxo-1,3,2-dioxaphosphorinane (TMP) using (i-C 4 H 9 ) 3 Al as the initiator. The chemical structure was characterized by 1 H nuclear magnetic resonance and Fourier transform infrared. The respective reactivity ratios of TMC and TMP were determined using the Kelen±Tu È do Ès method. Conversion studies showed that the composition of the copolymer agree with the feed composition at high conversions.

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