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Synthesis and Characterization of New Niobium Hydridotris(3,5-dimethylpyrazol-1-yl)borato Complexes

✍ Scribed by Antiñolo, A.; Carrillo-Hermosilla, F.; Fernández-Baeza, J.; Lanfranchi, M.; Lara-Sánchez, A.; Otero, A.; Palomares, E.; Pellinghelli, M. A.; Rodriguez, A. M.


Book ID
126923752
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
87 KB
Volume
17
Category
Article
ISSN
0276-7333

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One of the frequently used ligands, hydridotris(3,5-dimethylpyrazol-1 -yl) borate, and its thallium complex were fully characterized by multinuclear NMR. New 16N,20'T coupling constants were measured. A dynamic process, with an activation energy of 65 kJ mol-', which corresponds to the nitrogen-thal