✦ LIBER ✦

Multinuclear Magnetic Resonance (1H, 11B, 13C, 15N and 205Tl) Study of Thallium Hydridotris(3,5-dimethylpyrazol-1-yl)borate

✍ Scribed by D. Sanz; R. M. Claramunt; J. Glaser; S. Trofimenko; J. Elguero

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 271 KB
Volume: 34
Category: Article
ISSN: 0749-1581
DOI: 10.1002/(sici)1097-458x(199610)34:10<843::aid-omr1918>3.0.co;2-g

No coin nor oath required. For personal study only.

✦ Synopsis

One of the frequently used ligands, hydridotris(3,5-dimethylpyrazol-1 -yl) borate, and its thallium complex were fully characterized by multinuclear NMR. New 16N,20'T coupling constants were measured. A dynamic process, with an activation energy of 65 kJ mol-', which corresponds to the nitrogen-thallium bond breaking, is observed in these compounds.

📜 SIMILAR VOLUMES

Multinuclear Magnetic Resonance (1H, 11B

Multinuclear Magnetic Resonance (1H, 11B, 13C, 15N and 205Tl) Study of Thallium Hydridotris(3,5-dimethylpyrazol-1-yl)borate

✍ Dionisia Sanz; Rosa María Claramunt; Julius Glaser; Sviatoslaw Trofimenko; Jose 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 333 KB

An even more pronounced effect is observed in the 13C NMR spectra of spiro steroids. Signals of axial carbon atoms [(C(aJ are shifted upfield by 1.2-6.6 ppm compared with the respective signal of equatorial carbons [(C(a,,)] of the same type (Tables 2 and3). The only exception is the pair of compoun

An 1H and 13C NMR spectroscopic study of

An 1H and 13C NMR spectroscopic study of the structure of potassium and thallium salts of tris- and tetrakis-(pyrazol-1-yl) borates in solution. Some 13C11B and 13C205Tl residual coupling constants

✍ C. López; D. Sanz; R.M. Claramunt; S. Trofimenko; J. Elguero 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 718 KB

Multinuclear (1H, 13C, 15N, 19F, 31P) on

Multinuclear (1H, 13C, 15N, 19F, 31P) one- and two-dimensional magnetic resonance study of tert-butylamino-tert-butyl-fluorophosphane, tert-butylimino-tert-butylphosphane and of its dimer formed by [1 + 2] cycloaddition

✍ Bernd Wrackmeyer; Christian Köhler 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 409 KB

## Abstract Multinuclear magnetic resonance studies (^1^H, ^13^C, ^15^N, ^31^P) of three phosphorus–nitrogen compounds [__tert__‐butylamino‐__tert__‐butylfluorophosphane (1), __tert__‐butylimino‐__tert__‐butylphosphane (2) and its dimer (3)], in which numerous one‐ and two‐dimensional NMR experimen