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Synthesis and Characterization of Na5[CoO2]CO3.

✍ Scribed by Mikhail Sofin; Eva M. Peters; Martin Jansen


Book ID
101944660
Publisher
John Wiley and Sons
Year
2003
Weight
61 KB
Volume
34
Category
Article
ISSN
0931-7597

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The electronic structure of the [(NH3)5C
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## SCCC MO cdculnlions of the [WH3)sCo02CoWH3)5 1 5i cation were carried out. On the basis ot' the results obtained, the mapnetic properties and bond characters of the compound are discussed. Fin;llly, the electronic structure ol the 0; group as a ligand is analyzed.

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For the first time ruby-red single crystals and powder samples of Na 5 [NiO 2 ][CO 3 ] were obtained via a redox reaction between nickel metal and CdO in the presence of Na 2 O and Na 2 CO 3 (molar ratios of CdO : Na 2 O : Na 2 CO 3 equal 1 : 3 : 2). The crystal structure has been refined from singl