Synthesis and characterization of Na5[Co(CO)3(P{(CH2)nC6H4-P-SO3}3)2], n = 1, 2, 3, and 6. Novel zwitterion
✍ Scribed by Tamas Bartik; Berit Bartik; Ipin Guo; Brian E. Hanson
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 641 KB
- Volume
- 480
- Category
- Article
- ISSN
- 0022-328X
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## Abstract An improved procedure for the preparation of the known H~2~O‐soluble hydrogenation and hydroformylation catalyst, [RuH(Cl)(CO)(__m__tppms)~3~] (__m__tppms=__meta__‐monosulfonated triphenylphosphine) was developed. In contrast to the methods reported earlier, this synthesis yields the co
SUNl4ARY reported. (Co(C0) I (C~HS)ZP-N(CHI) ICH(CH3) (Cdi,)] 1 2 are compared. Synthesis and molecular structure determination of the title compound are The W R spectra of (M~'I~(CO)\*(C~HS)IP-N(CHI) ICH(CH3) (C6Ha)I )Z and CRYSTAL STRUCTURE The crystals are monoclinic with ( I = 11.713(6), b -19.5