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Molecular Structure Determination and Spectroscopic Investigation of {Mn (CO)4 [S- (C6H5) 2P-N (CH3) [CH(CH3) (C6H5)]]}2

โœ Scribed by J. Meunier-Piret; M. van Meerssche; M. Gielen; I. Vanden Eynde

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
199 KB
Volume
93
Category
Article
ISSN
0037-9646

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โœฆ Synopsis

SUNl4ARY reported. (Co(C0) I (C~HS)ZP-N(CHI) ICH(CH3) (Cdi,)] 1 2 are compared. Synthesis and molecular structure determination of the title compound are The W R spectra of (M~'I~(CO)*(C~HS)IP-N(CHI) ICH(CH3) (C6Ha)I )Z and CRYSTAL STRUCTURE The crystals are monoclinic with ( I = 11.713(6), b -19.552(13), c -12.072 ( 8 ) A , 6 -103.82(5)'. The space group is P21, with two molecules in the unitcell. other atoms from DIRDIF-program(l). SHELX-program(2) with anisotropic thermal parameters for only some atoms (Mn, P, N, C(22) and C(43)). The last R-index is 0.093 for the 1789 observed reflec-

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โœ Dr. Fritz R. Kreissl; Dipl.-Chem. Peter Friedrich ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 215 KB ๐Ÿ‘ 1 views

The crystallographic dataC3] and the molecular dimensions of ( 4 ) and ( ) are almost identical. We thus have one of those rare cases in which analyses and spectraL4] are more significant in identifying the compounds than structure determination. The most important structural characteristic of ( 4 )