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Synthesis and Characterization of Monomeric Salicylaldiminato Lanthanide Complexes and Their Catalytic Behavior for Polymerization of ϵ-Caprolactone

✍ Scribed by Yu Long-Bao; Yao Ying-Ming; Shen Qi; Zhang Jing; Wu Li-Xin; Ye Ling


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
306 KB
Volume
21
Category
Article
ISSN
0256-7660

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✦ Synopsis


Project supported by the National N d Science Foundation d China (No. #xmrm).


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## Abstract The ring‐opening polymerization (ROP) of __ε__‐caprolactone (__ε__‐CL) using lanthanide thiolate complexes [(CH~3~C~5~H~4~)~2~Sm(μ‐SPh)(THF)] ~2~ (1) and Sm(SPh)~3~(HMPA)~3~ (2) as initiators has been investigated for the first time. Both of 1 and 2 were found to be highly efficient ini