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Synthesis and Structure of 1-Cyclopentylindenyl Lanthanide(II) Complexes and Their Catalytic Behavior for Polymerization of Acrylonitrile

✍ Scribed by Min-Hua Qi; Qi Shen; Xin-Qiang Gong; Zhi-Quan Shen; Lin-Hong Weng


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
403 KB
Volume
20
Category
Article
ISSN
0256-7660

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## Abstract Two methods to synthesize homoleptic guanidinate lanthanide complex are described. The samarium guanidinate complex [Sm{Ph~2~NC(NCy)~2~}~3~]Β·2C~7~H~8~ (1) can be synthesized by the metathesis reaction of lithium guanidinate with anhydrous samarium trichloride in a 3:1 molar ratio. The a