Synthesis and Characterization of Homole
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Liying Zhou; Yingming Yao; Yong Zhang; Mingqiang Xue; Jinglei Chen; Qi Shen
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Article
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2004
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John Wiley and Sons
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English
⚖ 134 KB
## Abstract Two methods to synthesize homoleptic guanidinate lanthanide complex are described. The samarium guanidinate complex [Sm{Ph~2~NC(NCy)~2~}~3~]·2C~7~H~8~ (1) can be synthesized by the metathesis reaction of lithium guanidinate with anhydrous samarium trichloride in a 3:1 molar ratio. The a