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Synthesis and Characterization of Lanthanide(III) Bis(guanidinate) Derivatives and the Catalytic Activity of Methyllanthanide Bis(guanidinate) Complexes for the Polymerization of ϵ-Caprolactone and Methyl Methacrylate

✍ Scribed by Yunjie Luo; Yingming Yao; Qi Shen; Kaibei Yu; Linhong Weng


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
129 KB
Volume
2003
Category
Article
ISSN
1434-1948

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## Abstract Two methods to synthesize homoleptic guanidinate lanthanide complex are described. The samarium guanidinate complex [Sm{Ph~2~NC(NCy)~2~}~3~]·2C~7~H~8~ (1) can be synthesized by the metathesis reaction of lithium guanidinate with anhydrous samarium trichloride in a 3:1 molar ratio. The a