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Synthesis, characterization and application of benzyl-substituted cyclopentadienyl lanthanide complexes as catalyst precursors for the syndiotactic polymerization of methyl methacrylate

โœ Scribed by Yan-Long Qian; Muhammad Baia; Xiao-Min D. Xie; Ji-Ling Huang


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
479 KB
Volume
22
Category
Article
ISSN
0256-7660

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โœ Xiaomin Xie; Jiling Huang ๐Ÿ“‚ Article ๐Ÿ“… 2004 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 161 KB ๐Ÿ‘ 1 views

The synthesis and characterization of a series of new pendant phenyl substituted cyclopentadienyl lanthanide chlorides are reported. The analytical data of 3a-3e point to the formation of monomeric and unsolvated complexes, (PhCMe 2 C 5 H 4 ) 2 LnCl (Ln = Er (3a), Sm (3b), Gd (3c), Y (3d), Nd (3e));