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Synthesis and characterization of homo-dinuclear complexes [M2(dea)2(H2O)4], [M2(dea)2(Bipy)2] and [Fe2(dea)2(H2O)2(Cl)2] (M=Co, Ni or Cu; H2dea=diethanolamine): 57Fe Mössbauer and electrochemical investigations

✍ Scribed by Siddiqi, Zafar A.; Siddique, Armeen; Shahid, M.; Sharma, Prashant K.; Khalid, Mohd.; Yogi, Anjuli


Book ID
121709087
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
507 KB
Volume
1036
Category
Article
ISSN
0022-2860

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The Miissbauer spectra of iron and cobalt fluoroborate hexahydrate show a change by a factor of two in the quadrupole interaction near 2%) K and 185 K, respectively, togtther with a sudden drop in resonance fraction. This behaviour is explained as a first order phase transition in which the axial pa