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Crystal structures of mixed ligand complexes containing saccharinate and nicotinamide: [Cu(saccharinato)2(nicotinamide) (H2O)]⋅(H2O) and [M(nicotinamide)2(H2O)4]⋅(saccharinate)2(M = Ni2+, Co2+)

✍ Scribed by Semiha Çakir; Iclal Bulut; Katsuyuki Aoki

Book ID
111569444
Publisher
Springer
Year
2003
Tongue
English
Weight
215 KB
Volume
33
Category
Article
ISSN
1572-8854

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The crystal structure determination of the title compounds showed that they are isomorphous, revealing the general formula [M(H,O),(py)z](sac),. 4H,O. Their structures are built up of [M(H,0),(py)z]2' cations, saccharinato anions and non-coordinated water molecules. The metal atom lies on the invers

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Structural features of a new [Fe(nicotinamide)2(H2O)4]·[Fe(H2O)6]·(SO4)2·2H2O complex
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A new nicotinamide complex of Fe(II) cation was prepared by reaction between ferrous sulfate and nicotinamide in aqueous solution. The complex was characterized on the basis of elemental analysis, FT IR and UV-VIS spectroscopy, electrochemistry (cyclic voltammetry) and X-ray crystallography. The com