Synthesis and characterization of cobalt(III) tetraaza macrocyclic complexes containing chloro and azido ligands
β Scribed by Ki-Young Choi; Hee-Kune Lee; Ki-Jung Kim; Haiil Ryu; Kyu-Chul Lee; Jaejung Ko; Moon-Jip Kim
- Book ID
- 106547183
- Publisher
- Springer
- Year
- 2006
- Tongue
- English
- Weight
- 255 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0340-4285
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Metal phthalocyanines (M = Cu, Ni, Co, SnCI2) 3-6 containing four 14-membered tetraaza macrocycles have been prepared. Detosylation of the aza functions has provided donor sites for binding four Ni2+ ions giving a pentanuclear com-plex which is extremely soluble in polar solvents. The mass spectrum
The dimerization of complex (1), [Fe(TIM)(H20)2] 2+ (TIM = 2,3,3, in aerated aqueous solution results in formation of the binuclear complex (2), [(H20)(TIM )-Fe--O--O--Fe(TIM)(H20)] 4 Β§ Complex (2) has been characterized by elemental analysis, spectroscopy and electrochemical data.