Synthesis and characterization of a binuclear iron-μ-peroxo complex of a tetraaza macrocyclic ligand

✍ Scribed by Noel M. Levy; Eduardo Stadler; Antonio S. Mangrich; Mauricio A. C. Melo; Valderes Drago

• Publisher: Springer
• Year: 1993
• Tongue: English
• Weight: 487 KB
• Volume: 18
• Category: Article
• ISSN: 0340-4285
• DOI: 10.1007/bf00191136

✦ Synopsis

The dimerization of complex (1), [Fe(TIM)(H20)2] 2+ (TIM = 2,3,3, in aerated aqueous solution results in formation of the binuclear complex (2), [(H20)(TIM )-Fe--O--O--Fe(TIM)(H20)] 4 § Complex (2) has been characterized by elemental analysis, spectroscopy and electrochemical data.