Synthesis and characterization of a tetraphosphine macrocyclic ligand and its manganese(II) complexes
✍ Scribed by Guang Qing Li; Rakesh Govind
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 322 KB
- Volume
- 231
- Category
- Article
- ISSN
- 0020-1693
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## Abstract The preparation of a macrocyclic diphosphine ligand 5 incorporating a binaphthyl unit and its Ni^II^ and Pd^II^ complexes, 6 and 7, is described. A complete assignment of ^1^H,‐ ^13^C‐, and ^31^P‐NMR data on the basis of 2D NMR spectroscopy (^1^H, ^1^H‐, ^13^C, ^1^H‐, ^31^P, ^1^H‐, ^31^
## Abstract Two novel adducts of formula Mn(hfaC)~2~(NITPhCLI)~2~ (1) and Mn(hfac)2(IMHPhCl)I~2~(NIT‐PhCl) 0.5H~2~O (2), where hfac = hexafluoroacetylacetonate, NITPhCI = 2–(3‐chlorophenyl)‐4,4,5,5‐tetramethylimidazolyl‐1‐oxyl‐3‐oxide, IMHPhCl = 2‐(3‐chlorophenyl)‐4, 4, 5, 5‐tetramethylimidazolyl‐3