A dinuclear manganese complex ([Mn 2 L(ยต-OAc) 2 ]PF 6 ) has been synthesized, where L is the trianion of 2,6-bis{[(2-hydroxy-3,5-di-tert-butylbenzyl)(2-pyridylmethyl)amino]-methyl}-4-methylphenol, a ligand with three phenolate groups. The two pseudo-octahedrally coordinated Mn ions are bridged via t
โฆ LIBER โฆ
Synthesis and characterization of a manganese(III) complex with a new unsymmetrical chelating ligand
โ Scribed by Kouichi Inamoto; Masayuki Koikawa; Michio Nakashima; Tadashi Tokii
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 341 KB
- Volume
- 249
- Category
- Article
- ISSN
- 0020-1693
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## Abstract The preparation and characterization of lithium and iron(II) complexes containing a potentially tridentate biphenolate phosphane ligand are reported. Deprotonation of 2,2โฒโphenylphosphanylโbis(4,6โdiโ__tert__โbutylphenol) (H~2~L^Ph^) with one or two equivalents of __n__BuLi in diethyl e