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Synthesis and Characterization of Chiral Group 4 Metallocene Alkyne Complexes: (η 5 -menthyl-C 5 H 4 ) 2 M(η 2 -Me 3 SiC 2 SiMe 3 ), M = Ti, Zr ⊥

✍ Scribed by Klahn, Marcus; Baumann, Wolfgang; Arndt, Perdita; Burlakov, Vladimir V.; Schareina, Thomas; Spannenberg, Anke; Rosenthal, Uwe


Book ID
127032290
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
98 KB
Volume
28
Category
Article
ISSN
0276-7333

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The Influence of the Ligands Cp*(η5-C5Me
✍ Paul-Michael Pellny; Vladimir V. Burlakov; Wolfgang Baumann; Anke Spannenberg; U 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 213 KB 👁 1 views

The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,