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Synthesis and characterization of a lead(II) complex [Pb(phen)(H2O)(NO3)2] (phen = 1,10-phenanthroline)

โœ Scribed by Quanzheng Zhang; Canzhong Lu


Publisher
Springer
Year
2005
Tongue
English
Weight
89 KB
Volume
35
Category
Article
ISSN
1572-8854

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The single crystal X-ray data of a mixed anions complex of Pb II with 1,10-Phenantroline, [Pb(phen)(O 2 CCH 3 )-(O 2 NO)], shows the complex to be polymeric as a result of acetate ligand bridging. The Pb atom has an asymmetrical eightfold coordination of two nitrogen atoms of the 1,10phenanthroline

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Dark blue plate-like crystals of [Cu 2 (phen) 2 (H 2 O) 2 (OH) 2 ](HCO 3 ) 2 ยด6 H 2 O were obtained from a CH 3 OHยฑH 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), sebacic acid and Na 2 CO 3 . The crystal structure (triclinic, P 1 (no. 2), a = 8.118(1), b = 9.624(1), c = 10.536(1) A รŠ