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Synthesis and characterisation of silver, zinc and cadmium compounds with an N3O2 Schiff base macrocycle: the crystal and molecular structures of the silver(I) and cadmium(II) complexes

✍ Scribed by Laura Valencia; Harry Adams; Rufina Bastida; David E Fenton; Alejandro Macı́as

Publisher: Elsevier Science
Year: 2001
Tongue: English
Weight: 158 KB
Volume: 317
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(01)00322-x

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✦ Synopsis

The metal-templated cyclocondensation of 2,6-diformylpyridine and 1,4-bis(2-aminophenoxy)butane in the presence of silver(I), zinc(II) and cadmium(II) salts gave the following di-imine macrocyclic complexes: 4) and [CdL(NO 3 )(CH 3 OH)](NO 3 ) (5) (L= macrocyclic ligand). All compounds have been characterised by microanalysis, IR, conductivity measurements, MS-FAB and 1 H NMR spectroscopic studies. Compounds 1, 4 and 5 were also studied by single-crystal X-ray diffraction.

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