✦ LIBER ✦
Synthesis and Characterization of Some Metal Complexes with New Nitrogen–Oxygen Donor Macrocyclic Ligands – X-ray Crystal Structures of a 26-Membered Reduced Monoprotonated Macrocycle and a 20-Membered Pendant-Arm Schiff-Base Macrocyclic Cadmium(II) Complex
✍ Scribed by Manuel Vicente; Carlos Lodeiro; Harry Adams; Rufina Bastida; Andrés de Blas; David E. Fenton; Alejandro Macías; Adolfo Rodríguez; Teresa Rodríguez-Blas
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 377 KB
- Volume
- 2000
- Category
- Article
- ISSN
- 1434-1948
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✦ Synopsis
New series of macrocyclic Schiff-base lanthanide(III), yttrium(III), and cadmium(II) complexes, [M(1)]X n (X = NO 3 -, M = Y, Ln = La-Yb except Pm and Dy; X = ClO 4 -, M = Cd, La, Ce, Pr, Sm, Gd, or Er) and [M(3)]X n (X = NO 3 -, M = Dy; X = ClO 4 -, M = Er and Cd), have been prepared by cyclocondensation of O 1 ,O 7 -bis(2-formylphenyl)-1,4,7-trioxaheptane with O 1 ,O 7 -bis(2-aninyl)-1,4,7-trioxaheptane (1) or tris(2-aminoethyl)amine (3) in the presence of the appropriate metal