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Synthesis and characterisation of a new chiral ruthenium picket-fence porphyrin and its use in chiral recognition of racemic isocyanides

✍ Scribed by Erwan Galardon; Michael Lukas; Paul Le Maux; Gérard Simonneaux

Book ID
104261083
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
205 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

The preparation of a new chiral porphyrin bearing eight optically active pickets, four on each side of the porphyrin plane is described. Chiral recognition in the complexation of racemic isocyanide to the ruthenium compound leads to the formation of three stereoisomers with low stereoselectivity (15%).

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