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Synthesis of a new chiral porphyrin ligand and its Mn (III) complex as catalyst in asymmetric alkene epoxidation

✍ Scribed by Gottfried Proess; Laszlo Hevesi


Publisher
Elsevier Science
Year
1993
Weight
459 KB
Volume
80
Category
Article
ISSN
0304-5102

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Synthesis of chiral Mn(III)-meso-tetraki
✍ Stefano Banfi; Amedea Manfredi; Fernando Montanari; Gianluca Pozzi; Silvio Quici πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 801 KB

The synthesis of Mn(III)-complexes of new chiral porphyrins la and lb prepared by condensation of enantiomerically pure [2.2]-p-cyclophane-4-carbaldehyde and pyrrole are described. These compounds were used as catalysts in epoxidation reactions of prochiral alkenes, carried out in the presence of aq