## Abstract Methyl 2,6,10‐trimethyltridecanoate (1), the male‐produced attractant pheromone of the South American soybean pest, __Euschistus heros__, and that of __E. obscurus__, was synthesized as a stereoisomeric mixture and identified by a comparison with the natural product on the basis of GC a
Synthesis and Biological Activity of Methyl 2,6,10-Trimethyldodecanoate and Methyl 2,6,10-Trimethyltridecanoate: Male-Produced Sexual Pheromones of Stink Bugs Euschistus heros and Piezodorus guildinii
✍ Scribed by Paulo H. G. Zarbin; Aurélia Reckziegel; Ernst Plass; Miguel Borges; Wittko Francke
- Book ID
- 111561970
- Publisher
- Springer
- Year
- 2000
- Tongue
- English
- Weight
- 141 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0098-0331
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## Abstract All of the eight possible stereoisomers of methyl 2,6,10‐trimethyltridecanoate (1), the male‐produced attractant pheromone of the South American soybean pest, __Euschistus heros__, and that of __E. obscurus__, are synthesized by starting from the enantiomers of citronellol (2) and methy
The enantioselective syntheses of two stereoisomers, (2R,6S,10S) and (2S,6S,10S), of methyl 2,6,10-trimethyldodecanote, out of eight possible isomers, are described , employing the stereoselective hydroboration of (-)-isopulegol (2) and (+)-neo-isopulegol (2a) as the key reaction.
## Abstract The synthesis of four stereoisomers of the female‐produced sex pheromone [(2R,6R,10R)‐, (2S,6R,10R)‐, (2S,6S,10S)‐, and (2R,6S,10S)‐1a] of the rice moth (Corcyra cephalonica) was achieved by starting from (R)‐2a, (R)‐ or (S)‐3a, and (R)‐ or (S)‐4 and using alkylation of alkyl phenyl sul