## Abstract Methyl 2,6,10‐trimethyltridecanoate (1), the male‐produced attractant pheromone of the South American soybean pest, __Euschistus heros__, and that of __E. obscurus__, was synthesized as a stereoisomeric mixture and identified by a comparison with the natural product on the basis of GC a
Pheromone Synthesis, CLXVII. Synthesis of All of the Eight Stereoisomers of Methyl 2,6,10-Trimethyltridecanoate, the Male-Produced Pheromone of the Stink Bugs,Euschistus heros andE. obscurus
✍ Scribed by Mori, Kenji ;Murata, Noriaki
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 917 KB
- Volume
- 1994
- Category
- Article
- ISSN
- 0947-3440
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
All of the eight possible stereoisomers of methyl 2,6,10‐trimethyltridecanoate (1), the male‐produced attractant pheromone of the South American soybean pest, Euschistus heros, and that of E. obscurus, are synthesized by starting from the enantiomers of citronellol (2) and methyl 3‐hydroxy‐2‐methylpropanoate (9).
📜 SIMILAR VOLUMES
## Abstract The synthesis of the four stereoisomers of 6,10,13‐trimethyl‐1‐tetradecanol (1a), the male‐produced aggregation pheromone of the predatory stink bug __Stiretrus anchorago__, was achieved by starting from (__R__)‐citronellol (2a), methyl (__R__)‐ or (__S__)‐3‐hydroxy‐2‐methylpropanoate (
## Abstract The synthesis of four stereoisomers of the female‐produced sex pheromone [(2R,6R,10R)‐, (2S,6R,10R)‐, (2S,6S,10S)‐, and (2R,6S,10S)‐1a] of the rice moth (Corcyra cephalonica) was achieved by starting from (R)‐2a, (R)‐ or (S)‐3a, and (R)‐ or (S)‐4 and using alkylation of alkyl phenyl sul
## Abstract Both the enantiomers of rhynchophorol [(__E__)‐6‐methyl‐2‐hepten‐4‐ol (1)], the male‐produced aggregation pheromone of the American palm weevil (__Rhynchophorus palmarum__), have been synthesized by reducing their precursors, (__R__)‐ and (__S__)‐6‐methyl‐2‐heptyn‐4‐ol (2), which have b
## Abstract The relative configuration of the naturally occurring 3‐methyl‐4‐octanol (1), the male‐produced aggregation pheromone of __Rhynchophorus phoenicis__, was determined as __syn__ by a GC comparison of the synthetic (±)‐__syn__‐ and (±)‐__anti__‐1 with the natural product. Enantioselective