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Pheromone Synthesis, CXLV. Synthesis of the Enantiomers of Rhynchophorol [(E)-6-Methyl-2-hepten-4-ol], the Male-Produced Aggregation Pheromone of the American Palm Weevil,Rhynchophorus palmarum

✍ Scribed by Mori, Kenji ;Ishigami, Ken

Publisher: John Wiley and Sons
Year: 1992
Tongue: English
Weight: 437 KB
Volume: 1992
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.1992199201196

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✦ Synopsis

Abstract

Both the enantiomers of rhynchophorol [(E)‐6‐methyl‐2‐hepten‐4‐ol (1)], the male‐produced aggregation pheromone of the American palm weevil (Rhynchophorus palmarum), have been synthesized by reducing their precursors, (R)‐ and (S)‐6‐methyl‐2‐heptyn‐4‐ol (2), which have been prepared by lipasemediated asymmetric hydrolysis of the corresponding acetate and propionate.

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