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Pheromone synthesis, CXXXI. Synthesis of the four stereoisomers of 6,10,13-trimethyl-1-tetradecanol, the aggregation pheromone of predatory stink bug,Stiretrus anchorago

✍ Scribed by Mori, Kenji ;Wu, Jiang

Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
601 KB
Volume
1991
Category
Article
ISSN
0947-3440

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✦ Synopsis

Abstract

The synthesis of the four stereoisomers of 6,10,13‐trimethyl‐1‐tetradecanol (1a), the male‐produced aggregation pheromone of the predatory stink bug Stiretrus anchorago, was achieved by starting from (R)‐citronellol (2a), methyl (R)‐ or (S)‐3‐hydroxy‐2‐methylpropanoate (10) and 4‐chloro‐1‐butanol (12a).

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