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Synthesis and Applications of a Novel Polymer-Supported EEDQ Reagent

✍ Scribed by Kakarla, Ramesh; Li, Guo; Gerritz, Samuel W.

Book ID
120089402
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
16 KB
Volume
10
Category
Article
ISSN
1520-4766

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πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Synthesis and Appli
ChemInform Abstract: Synthesis and Applications of a Novel Polymer-Supported EEDQ Reagent.
✍ Ramesh Kakarla; Guo Li; Samuel W. Gerritz πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons βš– 40 KB πŸ‘ 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

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A commercially available and inexpensive compound, 3-amino-1,2,4-dithiazole-5-thione (ADTT), has been attached onto a hydroxyl resin via a succinic acid linker. The polymer-supported ADTT is an efficient sulfur-transfer reagent for the solution-phase synthesis of phosphorothioates.

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A novel polymer-supported triacetoxyborohydride reagent for reductive amination of aldehydes and ketones is reported. The bound reagent was found to be shelf-stable and provided broad scope and reactivity in reductive amination reactions under mild reaction conditions. Streamlined protocols for its