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Synthesis and Anionic Polymerization of Isocyanates Bearing a Carbamate Group

โœ Scribed by Maeda, Katsuhiro; Matsunaga, Mamiko; Yamada, Hiroshi; Okamoto, Yoshio


Book ID
126951509
Publisher
Nature Publishing Group
Year
1997
Tongue
English
Weight
751 KB
Volume
29
Category
Article
ISSN
0032-3896

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Lanthanoid isopropoxide as a novel initi
โœ Naoko Fukuwatari; Hiroshi Sugimoto; Shohei Inoue ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 390 KB

Lanthanum isopropoxide was found to serve as a novel anionic initiator for the polymerization of hexyl isocyanate affording poly(hexy1 isocyanate) with very high molecular weight (M, > lo6) under appropriate conditions. Other lanthanoid alkoxides, such as samarium, ytterbium and yttrium isopropoxide