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Synthesis and radical polymerization of spiroorthocarbonates bearing exo-methylene groups

โœ Scribed by Sanda, Fumio; Takata, Toshikazu; Endo, Takeshi


Book ID
127220673
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
714 KB
Volume
26
Category
Article
ISSN
0024-9297

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โœ Fumio Sanda; Toshikazu Takata; Takeshi Endo ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 433 KB ๐Ÿ‘ 1 views

Molecular orbital studies were carried out to compare the easiness of ring-opening in the radical polymerization of spiro-orthocarbonates bearing exo-methylene groups at a-position of the ether oxygen, spiro[2,4-benzodioxepine-4'-methylene-3,2'-[1,3]-dioxolane] (l), and at /%position of the ether ox

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Synthesis and radical polymerization of novel vinylcyclopropanes; 1-carboethoxy-2-trimethylsilyl-2-vinylcyclopropane (1a) and 1-carboethoxy-2-(1-trimethylsilyl)-vinylcyclopropane (1b), were examined. 1a and 1b were prepared by the coupling reaction of 2-trimethylsilylbutadiene with ethyl diazoacetat

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A styrene derivative (1) bearing kojic acid moieties was prepared by t h e base-catalyzed reaction of p-formylstyrene with kojic acid. Hydroxyl groups in 1 were subjected to acetylation. Although 1 did not undergo radical polymerization, the acetylated styrene derivative (2) showed good radical homo